📋 Table of Contents
- What is MFI (Melt Flow Index)?
- What is MVR (Melt Volume Rate)?
- MFI vs MVR: Key Differences Side by Side
- Test Principle: What the MFI Apparatus Actually Measures
- ASTM D1238 and ISO 1133 — The Governing Standards
- Test Conditions: Temperature and Load for Every Major Polymer
- Method A vs Method B — When to Use Each
- Converting Between MFI and MVR
- How to Interpret MFI Values
- MFI as a Quality Control Tool
- The Four MFI Tester Models from International Equipments
- Tips for Accurate and Reproducible MFI Results
- Frequently Asked Questions
MFI and MVR are both outputs of the same instrument — the Melt Flow Index Tester — but they measure different things, use different calculations, and are suited to different materials and applications. Understanding the difference is essential for choosing the right test condition, the right tester model, and interpreting your results correctly.
The Melt Flow Index test is arguably the single most widely performed quality control test in the plastics industry. It is run on virtually every polymer — HDPE, PP, LDPE, LLDPE, PVC, ABS, Nylon, PC — at every stage of the supply chain: raw material acceptance, compounding quality control, production monitoring, and incoming inspection of finished products. Yet despite its ubiquity, confusion about MFI vs MVR, Method A vs Method B, and test condition selection is extremely common.
What is Melt Flow Index (MFI)?
Melt Flow Index (MFI) — also officially called Melt Flow Rate (MFR) or Melt Mass-Flow Rate (MFR) in ISO 1133 — is a measure of the ease of flow of a molten polymer through a standardised capillary die under a defined load and temperature.
MFI is expressed in grams per 10 minutes (g/10 min). It is measured by Method A — the mass method — in which extrudate cut-offs are weighed to calculate the mass of polymer that flows through the die in 10 minutes.
MFI (g/10 min) = mass of extrudate (g) × [600 / cut time (s)]
Where cut time = interval between cuts (typically 5–30 seconds depending on MFI range)
What MFI tells you: A higher MFI indicates a lower-viscosity melt — which generally means lower molecular weight, more chain scission from thermal degradation, or higher levels of lubricants/processing aids. A lower MFI indicates higher viscosity — higher molecular weight polymer with better long-term mechanical properties.
What is Melt Volume Rate (MVR)?
Melt Volume Rate (MVR) — also called Melt Volume-Flow Rate — is also defined in ASTM D1238 and ISO 1133, but measures the volume of polymer extruded rather than the mass. It is expressed in cubic centimetres per 10 minutes (cm³/10 min) and measured by Method B — the volume method.
In Method B (MVR), the apparatus measures the displacement of the piston using a position encoder rather than weighing cut-off samples. As the piston descends under the test load, the encoder records the distance travelled in a defined time, from which the extruded volume is calculated.
MVR (cm³/10 min) = A × L × [600 / t]
A
Piston cross-section area (cm²)
L
Piston travel distance (cm)
t
Travel time (seconds)
MFI vs MVR: Key Differences Side by Side
| Parameter | MFI (Method A) | MVR (Method B) |
|---|---|---|
| Full name | Melt Flow Index / Melt Flow Rate (MFR) | Melt Volume Rate (MVR) |
| ISO 1133 term | Melt Mass-Flow Rate (MFR) | Melt Volume-Flow Rate (MVR) |
| ASTM D1238 method | Method A | Method B |
| Unit | g/10 min | cm³/10 min |
| Measurement principle | Cut & weigh extrudate samples | Piston position encoder — measures volume directly |
| Density dependence | Yes — result influenced by melt density | No — independent of melt density |
| Best for | Unfilled polymers, routine QC, IS 4984 HDPE pipe testing | Filled/reinforced compounds, density comparison, R&D |
| Accuracy for filled compounds | Lower — density variation affects result | Higher — volume is independent of filler density |
| Can calculate MVR from MFI? | Only if melt density is known: MVR = MFI / melt density | Directly measured |
| Instrument required | Any MFI tester (Method A or A&B models) | MFI tester with piston position encoder (Method A&B model) |
Test Principle: What the MFI Apparatus Actually Measures
Despite its simplicity, the MFI test is a capillary rheometer operating at a single shear rate — a fundamental measurement of polymer viscosity under processing-like conditions. Here is what happens inside the apparatus:
🔥Barrel heating
The steel barrel is heated to the test temperature (e.g. 190°C for PE) and held stable within ±0.5°C. The polymer sample (3–5 g) is loaded and allowed to preheat for exactly 5–6 minutes to achieve temperature equilibrium.
⚖️Load application
A standardised dead-weight load (e.g. 2.16 kg, 5 kg, or 10 kg) is applied via a piston on top of the molten polymer, creating a defined pressure difference across the die.
🕳️Extrusion through die
Molten polymer is extruded through the hardened steel die (bore 2.095 mm dia × 8.000 mm long) under the applied pressure. The flow rate is determined by the polymer viscosity.
📏Measurement
Method A: Extrudate cut at defined intervals, each cut-off weighed on an analytical balance. Method B: Piston displacement measured by encoder — no cutting needed.
ASTM D1238 and ISO 1133 — The Governing Standards
Two standards govern MFI and MVR testing worldwide:
📋 ASTM D1238
Standard Test Method for Melt Flow Rates of Thermoplastics by Extrusion Plastometer
▸ Used widely in USA, India (IS references ASTM)
▸ Defines Method A (mass) and Method B (volume)
▸ Specifies test conditions for all major polymers
▸ Die bore: 2.095 mm × 8.000 mm
▸ Referenced by IS 4984, IS 4985, IS 14885
📋 ISO 1133
Plastics — Determination of the Melt Mass-Flow Rate (MFR) and Melt Volume-Flow Rate (MVR)
▸ International standard — used in Europe, globally
▸ Defines MFR (=MFI) and MVR
▸ Consistent die dimensions with ASTM
▸ Referenced by EN 12201, EN ISO 1133
▸ Part 1: Standard conditions; Part 2: Temperature-sensitive polymers
Test Conditions: Temperature and Load for Every Major Polymer
MFI results are only meaningful when the test conditions are specified. The same polymer can give dramatically different MFI values at different temperatures and loads. Always report MFI with the full condition, e.g. MFI (190/5) = 0.8 g/10 min meaning 190°C temperature, 5 kg load.
| Polymer | Standard | Temperature | Load | Typical MFI Range | Common Applications |
|---|---|---|---|---|---|
| HDPE — pipe grade | IS 4984 / ASTM D1238 | 190°C | 5.0 kg | 0.2 – 1.5 g/10 min | Pipe extrusion quality control |
| HDPE — general / film | ASTM D1238 | 190°C | 2.16 kg | 0.1 – 5.0 g/10 min | Blown film, injection moulding |
| LDPE / LLDPE | ASTM D1238 / ISO 1133 | 190°C | 2.16 kg | 0.3 – 30 g/10 min | Packaging film, coating |
| Polypropylene (PP) | ASTM D1238 / ISO 1133 | 230°C | 2.16 kg | 0.5 – 50 g/10 min | Fibres, injection, pipe |
| PVC (rigid) | ISO 1133 | 180°C | 10 kg | Typically < 5 g/10 min | Pipe, profiles |
| ABS | ASTM D1238 | 220°C | 10 kg | 1 – 20 g/10 min | Injection moulding |
| Polycarbonate (PC) | ASTM D1238 | 300°C | 1.2 kg | 5 – 40 g/10 min | Optical, engineering |
| Nylon 6 (PA 6) | ISO 1133 | 235°C | 1.0 kg | 2 – 50 g/10 min | Fibres, engineering plastics |
| Nylon 66 (PA 66) | ISO 1133 | 275°C | 1.0 kg | 1 – 30 g/10 min | Engineering applications |
| POM (Acetal) | ASTM D1238 | 190°C | 2.16 kg | 1 – 30 g/10 min | Precision parts |
| EVA | ASTM D1238 | 190°C | 2.16 kg | 0.3 – 150 g/10 min | Adhesives, film |
| TPE / Elastomer | ASTM D1238 | 190°C | 5.0 kg | Varies widely | Seals, hoses, overmoulding |
Method A vs Method B — When to Use Each
⚖️ Method A — Use When:
- ✓Testing unfilled or lightly filled polymers (HDPE, PP, LDPE, PVC)
- ✓Routine production QC — fast, simple, no encoder needed
- ✓IS 4984 HDPE pipe raw material and finished pipe testing
- ✓Comparing batches of the same polymer type and grade
- ✓Laboratory has basic analytical balance available
- ✓Budget-conscious operations needing reliable pass/fail results
📐 Method B — Use When:
- ✓Testing highly filled or reinforced compounds (glass-filled, mineral-filled)
- ✓Comparing polymers with very different densities (PE vs PA 6 vs PC)
- ✓Density data is needed for processing calculations
- ✓R&D and compound development requiring both MFI and MVR
- ✓Converting between MFI and MVR (melt density calculation)
- ✓Specification requires MVR in cm³/10 min (European polymer specs)
Converting Between MFI and MVR
MFI and MVR are related through the melt density of the polymer at the test temperature. If you have one value, you can calculate the other — provided you know the melt density:
MFI = MVR × ρmelt
g/10 min = cm³/10 min × g/cm³
MVR = MFI / ρmelt
cm³/10 min = g/10 min ÷ g/cm³
Melt density reference values
| Polymer | Test Temp. | Typical Melt Density | Notes |
|---|---|---|---|
| HDPE | 190°C | 0.74 – 0.76 g/cm³ | Standard pipe/film grade |
| LDPE / LLDPE | 190°C | 0.74 – 0.76 g/cm³ | Similar to HDPE |
| PP | 230°C | 0.73 g/cm³ | Homopolymer and copolymer |
| ABS | 220°C | 0.98 – 1.02 g/cm³ | Acrylonitrile-butadiene-styrene |
| PC | 300°C | 1.14 – 1.18 g/cm³ | Polycarbonate |
Worked example
Example: HDPE compound tested at 190°C / 5 kg. Melt density = 0.75 g/cm³.
Method A result: MFI = 0.90 g/10 min
Method B result: MVR = MFI / ρmelt = 0.90 / 0.75 = 1.20 cm³/10 min
Or conversely, if MVR = 1.20 cm³/10 min:
MFI = MVR × ρmelt = 1.20 × 0.75 = 0.90 g/10 min
How to Interpret MFI Values
What does MFI actually tell you about the polymer?
| MFI Direction | Molecular Weight | Viscosity | Processing | Properties | Quality signal |
|---|---|---|---|---|---|
| Higher MFI → | Lower molecular weight | Lower melt viscosity | Easier to process | Weaker mechanical properties (generally) | May indicate thermal degradation |
| Lower MFI → | Higher molecular weight | Higher melt viscosity | Harder to process (higher pressures) | Better mechanical / ESCR properties | Preferred for pipe grade, load-bearing applications |
MFI ratio — compound vs finished product
One of the most powerful uses of MFI testing in production is to compare the MFI of the raw compound (as received) against the MFI of the finished extruded pipe or moulded part. Any significant increase in MFI of the finished product indicates thermal degradation during processing — molecular weight has been reduced by chain scission at excessive barrel temperatures.
MFI ratio (pipe/compound)
< 1.20
✓ Acceptable — normal processing degradation
MFI ratio
1.20 – 1.40
⚠ Warning — check barrel temperatures
MFI ratio
> 1.40
✗ Reject — excessive thermal degradation
MFI as a Quality Control Tool
In a well-run plastic products manufacturing operation, MFI testing is performed at multiple control points:
Stage 1
Incoming raw material
Test every lot of polymer compound from the supplier. Verify MFI matches specification. Reject lots outside tolerance before they enter production.
Stage 2
After compounding / masterbatch
Verify the compound MFI after adding additives, fillers or masterbatch. Ensure blending has not shifted MFI outside the processing window.
Stage 3
Start-up sample (first extrusion)
Test the first pipe / film / moulded part of each production run. Confirm process is running at the correct temperature profile before committing to full production.
Stage 4
In-process monitoring
Test samples every 2–4 hours during continuous production. Detect drift from barrel temperature fluctuations, screw wear, or raw material variation.
Stage 5
Finished product
Test representative finished samples before dispatch. Compare MFI ratio (finished / compound) to detect processing degradation per IS 4984.
Stage 6
Customer / third-party verification
Incoming inspection by pipe buyers, BIS auditors, or export certification bodies. MFI is always one of the first tests run.
The Four MFI Tester Models from International Equipments
International Equipments manufactures four MFI tester models, covering the full range from basic production QC to computerised R&D laboratories:
🔗 Related Products:
- → Melt Flow Index Tester — all 4 models — KAYJAY/2005/CE · KAYJAY/2006/AC · Computerised Method A · Computerised Method A&B
Tips for Accurate and Reproducible MFI Results
- 1Dry hygroscopic polymers before testing. Nylon (PA), PET, PC and POM absorb moisture from the air. Undried samples give high MFI values due to hydrolytic chain scission at test temperature. Dry at the manufacturer's recommended temperature (e.g. PA 6: 80°C for 4h) before MFI testing.
- 2Use the correct preheat time — exactly 5–6 minutes. Too short = barrel not at equilibrium, extrudate is at wrong temperature. Too long = thermal degradation of the sample in the barrel, falsely high MFI. Set a timer; don't estimate.
- 3Clean the die and barrel after every test. Residual degraded polymer from the previous test contaminates the next, particularly if different polymers are tested in sequence. Use the cleaning rod and fresh cotton swabs. Never use a metal tool inside the die bore — it will scratch and widen the bore.
- 4Use the right sample mass (3–5 g, typically). Too little sample means the barrel empties before sufficient cuts are made. Too much creates excessive back-pressure. Load approximately 3–5 g for most polymers — the barrel should not be completely emptied in less than 10 cut intervals.
- 5Check barrel and die temperature calibration regularly. Temperature drift of even ±2°C can shift MFI results significantly, particularly for polymers like PP where viscosity is highly temperature-sensitive. Calibrate with a NIST-traceable thermometer at least monthly.
- 6Discard the first cut for high-MFI materials. For polymers with MFI > 20 g/10 min, the initial extrudate contains pre-heated polymer from the preheat period. Discard the first cut and collect only subsequent cuts for weighing.
- 7Always run at least 3 cut-offs per specimen and average. Single cut-off results have high uncertainty. Three or more cuts from the same specimen, averaged, give the MFI for that specimen. For statistical reporting, test 5–10 specimens and report mean ± standard deviation.
- 8Compare MFI (compound) vs MFI (finished pipe) — it is a mandatory check. This ratio is the best single indicator of processing quality. A ratio > 1.20 triggers investigation; > 1.40 triggers batch rejection under IS 4984.
Key Takeaways
- ✓MFI (Melt Flow Index, g/10 min) and MVR (Melt Volume Rate, cm³/10 min) are both measured by the MFI tester — MFI by Method A (mass, cut & weigh), MVR by Method B (volume, piston encoder).
- ✓MFI is the standard for routine production QC and IS 4984 HDPE pipe testing. MVR is better for filled/reinforced compounds and European polymer specifications.
- ✓The two are related by melt density: MFI = MVR × ρmelt. The Computerised Method A&B tester calculates both simultaneously.
- ✓Always specify test conditions with results: temperature, load, and standard (e.g. 'MFI (190°C / 5 kg) = 0.8 g/10 min per ASTM D1238').
- ✓Higher MFI = lower molecular weight = lower viscosity = generally weaker mechanical properties. For HDPE pipes, lower MFI = better pressure resistance and ESCR.
- ✓The MFI ratio (finished pipe / raw compound) must not exceed 1.20 per IS 4984. A higher ratio indicates thermal degradation during extrusion.
- ✓International Equipments manufactures four MFI tester models from basic manual (KAYJAY/2005/CE) to computerised Method A&B — all CE and ISO certified.
Frequently Asked Questions
Common questions about MFI, MVR, ASTM D1238, test conditions, and MFI tester selection.